Li7Si2S7I_330K

Table 1 Crystal data and structure refinement for Li7Si2S7I_330K.
Identification code Li7Si2S7I_330K
Empirical formula ILi7S7Si2
Formula weight 456.08
Temperature/K 330.0
Crystal system monoclinic
Space group P21/n
a/Å 14.9844(4)
b/Å 6.05530(10)
c/Å 15.1935(4)
α/° 90
β/° 105.724(3)
γ/° 90
Volume/Å3 1326.99(6)
Z 4
ρcalcg/cm3 2.283
μ/mm‑1 3.367
F(000) 856.0
Crystal size/mm3 0.03 × 0.02 × 0.02
Radiation synchrotron (λ = 0.6889)
2Θ range for data collection/° 3.282 to 51.006
Index ranges -18 ≤ h ≤ 18, -7 ≤ k ≤ 7, -18 ≤ l ≤ 18
Reflections collected 16716
Independent reflections 2718 [Rint = 0.0477, Rsigma = 0.0232]
Data/restraints/parameters 2718/71/236
Goodness-of-fit on F2 1.059
Final R indexes [I>=2σ (I)] R1 = 0.0359, wR2 = 0.1083
Final R indexes [all data] R1 = 0.0373, wR2 = 0.1096
Largest diff. peak/hole / e Å-3 1.67/-0.64

 

Table 2 Fractional Atomic Coordinates (×104) and Equivalent Isotropic Displacement Parameters (Å2×103) for Li7Si2S7I_330K. Ueq is defined as 1/3 of the trace of the orthogonalised UIJ tensor.
AtomxyzU(eq)
Si15847.2(6)3496.7(16)3913.2(6)21.9(2)
Si25801.8(6)3555.6(16)1506.7(6)21.3(2)
Li14962(6)9278(17)2473(6)55(2)
Li26892(6)7654(19)3047(6)63(4)
Li33452(10)2761(19)2142(8)63(4)
Li44703(19)8790(50)4600(20)54(6)
Li56670(20)8080(70)5338(19)60(8)
Li63403(18)3530(60)4500(20)46(8)
Li75927(12)3890(30)6192(11)46(6)
Li84854(16)-800(40)229(14)75(8)
Li96826(15)8090(50)559(17)52(6)
Li105854(11)3690(40)-773(11)49(6)
Li113253(14)3270(60)-366(19)72(9)
Li12500010000500053(9)
Li137030(30)8180(90)5090(30)64(9)
Li144390(80)-2100(200)900(80)60(30)
Li154280(40)7780(120)3980(50)63(8)
I13122.6(2)7431.4(4)1964.4(2)31.26(14)
S14523.2(7)2071.5(18)3662.2(8)28.9(2)
S26779.8(8)2429.1(16)5138.0(8)30.5(3)
S35743.6(7)6945.7(17)3887.3(7)30.5(2)
S46511.4(7)2313.3(15)2876.0(7)23.8(2)
S54460.3(7)2195.8(17)1101.3(7)26.9(2)
S66658.5(8)2367.3(16)720.6(8)29.3(3)
S75818.6(7)7015.9(16)1513.5(7)28.1(2)

 

Table 3 Anisotropic Displacement Parameters (Å2×103) for Li7Si2S7I_330K. The Anisotropic displacement factor exponent takes the form: -2π2[h2a*2U11+2hka*b*U12+…].
AtomU11U22U33U23U13U12
Si121.7(5)22.3(5)21.7(5)-0.6(4)5.8(4)-0.8(4)
Si221.8(5)20.7(5)21.8(5)-0.2(4)6.7(4)-0.8(3)
Li146(4)61(5)57(5)3(4)15(4)1(4)
Li234(6)109(12)41(6)5(4)1(5)-12(4)
Li369(8)71(7)54(7)12(5)28(6)18(5)
Li450(8)53(11)65(12)21(9)24(8)5(7)
Li549(8)90(20)40(10)-12(12)13(6)2(11)
Li632(12)53(13)43(15)-25(12)-9(10)2(9)
Li745(9)50(12)44(9)7(8)16(7)19(8)
Li872(12)79(14)59(12)-31(10)-5(9)29(11)
Li946(11)59(14)56(12)-2(11)23(9)-11(11)
Li1033(8)80(16)32(8)15(8)7(6)13(9)
Li1133(9)110(20)74(16)39(16)15(10)1(12)
Li1254(11)54(12)60(15)22(12)30(10)-2(8)
Li1350(8)100(20)42(11)-7(14)14(8)4(11)
Li1460(40)60(40)60(40)-10(20)20(20)6(19)
Li1543(10)68(14)80(14)4(9)19(8)14(9)
I125.6(2)33.9(2)34.1(2)-1.22(9)7.84(14)-1.39(9)
S122.1(5)31.6(5)33.8(5)0.4(4)8.6(4)-4.5(4)
S225.7(5)41.1(6)23.3(5)1.4(3)4.3(4)5.4(3)
S335.7(5)22.7(5)34.2(5)-3.0(4)11.1(4)-0.4(4)
S421.9(5)27.0(5)22.2(5)0.4(3)5.6(4)3.5(3)
S520.9(5)30.6(5)27.6(5)-2.5(4)3.9(4)-4.1(3)
S628.3(5)35.7(6)25.7(5)-1.4(3)10.4(4)3.6(3)
S732.4(5)22.1(4)30.5(5)1.4(4)9.5(4)-1.3(4)

 

Table 4 Bond Lengths for Li7Si2S7I_330K.
AtomAtomLength/Å AtomAtomLength/Å
Si1S12.1015(14) Li6S322.46(3)
Si1S22.1035(15) Li7Li1263.07(2)
Si1S32.0938(14) Li7Li1521.07(7)
Si1S42.1994(14) Li7I122.891(16)
Si2S42.1967(13) Li7S122.560(19)
Si2S52.1040(14) Li7S22.468(16)
Si2S62.1032(14) Li7S322.525(18)
Si2S72.0955(14) Li8Li891.33(6)
Li1Li22.954(13) Li8Li962.94(3)
Li1Li313.034(15) Li8Li932.97(3)
Li1Li723.32(2) Li8Li1092.32(4)
Li1Li1033.11(2) Li8Li1193.16(3)
Li1Li1412.45(12) Li8Li141.57(13)
Li1Li152.90(7) Li8Li1492.87(14)
Li1I12.879(9) Li8S52.41(2)
Li1S112.684(10) Li8S592.64(2)
Li1S32.573(9) Li8S692.52(2)
Li1S412.894(9) Li8S762.47(2)
Li1S512.680(9) Li9Li103.42(3)
Li1S72.582(9) Li9Li1130.87(4)
Li2S32.442(10) Li9Li1433.44(13)
Li2S412.876(12) Li9S242.62(2)
Li2S642.460(9) Li9S442.98(2)
Li2S72.476(9) Li9S532.73(2)
Li3Li723.18(2) Li9S612.62(3)
Li3Li1033.34(2) Li9S72.45(2)
Li3I153.031(13) Li10Li1132.63(4)
Li3I163.265(12) Li10Li13103.06(4)
Li3I12.871(11) Li10Li1491.06(13)
Li3S12.465(13) Li10I132.756(17)
Li3S52.489(12) Li10S532.56(2)
Li4Li471.96(7) Li10S62.401(15)
Li4Li52.89(4) Li10S732.491(17)
Li4Li572.82(4) Li11Li13113.02(6)
Li4Li722.09(4) Li11S2122.56(2)
Li4Li120.98(3) Li11S52.55(2)
Li4Li151.16(8) Li11S632.71(3)
Li4Li1573.09(9) Li11S732.51(3)
Li4S122.63(3) Li12Li152.12(8)
Li4S112.42(3) Li12Li1572.12(8)
Li4S222.47(3) Li12S122.3299(11)
Li4S32.40(3) Li12S112.3299(11)
Li5Li621.02(5) Li12S213.0028(12)
Li5Li73.18(5) Li12S223.0028(12)
Li5Li122.68(3) Li12S372.9224(10)
Li5Li130.74(4) Li12S32.9225(10)
Li5Li1573.19(8) Li13I182.89(4)
Li5I182.83(3) Li13S212.60(5)
Li5S122.64(3) Li13S32.40(4)
Li5S212.66(4) Li13S642.63(4)
Li5S32.37(3) Li14I162.83(12)
Li6Li722.26(4) Li14S52.59(13)
Li6Li1263.14(3) Li14S692.54(12)
Li6Li1321.45(6) Li14S762.16(12)
Li6Li153.09(8) Li15I13.09(7)
Li6I152.80(2) Li15S112.69(7)
Li6S12.52(3) Li15S222.34(6)
Li6S222.54(3) Li15S32.30(6)

1+X,1+Y,+Z; 21-X,1-Y,1-Z; 31-X,1-Y,-Z; 43/2-X,1/2+Y,1/2-Z; 51/2-X,-1/2+Y,1/2-Z; 6+X,-1+Y,+Z; 71-X,2-Y,1-Z; 81/2+X,3/2-Y,1/2+Z; 91-X,-Y,-Z; 103/2-X,-1/2+Y,1/2-Z; 11-1/2+X,3/2-Y,-1/2+Z; 12-1/2+X,1/2-Y,-1/2+Z

 

Table 5 Bond Angles for Li7Si2S7I_330K.
AtomAtomAtomAngle/˚ AtomAtomAtomAngle/˚
S1Si1S2113.74(6) Li103Li11Li8990.0(8)
S1Si1S4108.94(6) Li103Li11Li131165.3(13)
S2Si1S4102.27(5) Li103Li11S6353.4(8)
S3Si1S1110.16(6) Li1311Li11Si2394.7(13)
S3Si1S2110.56(6) Li1311Li11Li8152.1(12)
S3Si1S4110.93(6) Li1311Li11Li89155.2(15)
S5Si2S4108.79(6) S212Li11Si23144.4(11)
S6Si2S4101.97(6) S212Li11Li8114.0(10)
S6Si2S5112.43(6) S212Li11Li89137.1(12)
S7Si2S4109.61(5) S212Li11Li103104.1(13)
S7Si2S5113.70(6) S212Li11Li131154.8(10)
S7Si2S6109.66(6) S212Li11S63108.2(11)
Li2Li1Li31155.1(5) S5Li11Si23108.5(8)
Li2Li1Li7298.6(4) S5Li11Li845.3(6)
Li2Li1Li103100.7(4) S5Li11Li8953.8(6)
Li31Li1Li7295.7(4) S5Li11Li10359.2(8)
Li31Li1Li10399.0(5) S5Li11Li1311108.0(14)
Li103Li1Li7292.3(6) S5Li11S21299.3(8)
Li141Li1Li2103(3) S5Li11S63111.2(13)
Li141Li1Li3191(3) S63Li11Si2341.0(4)
Li141Li1Li72108(3) S63Li11Li8133.9(9)
Li141Li1Li10317(3) S63Li11Li89112.6(9)
Li141Li1Li15124(4) S63Li11Li131154.4(11)
Li141Li1I164(3) S73Li11Si2341.3(3)
Li141Li1S11141(3) S73Li11Li869.5(8)
Li141Li1S3126(3) S73Li11Li8950.1(6)
Li141Li1S41118(3) S73Li11Li103103.0(9)
Li141Li1S5160(3) S73Li11Li1311133.8(13)
Li141Li1S751(3) S73Li11S212151.7(15)
Li15Li1Li2101.0(12) S73Li11S5101.2(8)
Li15Li1Li3186.6(12) S73Li11S6382.1(7)
Li15Li1Li7218.2(14) Li4Li12Li47179.997(11)
Li15Li1Li103109.3(16) Li47Li12Li587.8(17)
I1Li1Li2137.7(4) Li4Li12Li592.2(17)
I1Li1Li3167.0(3) Li47Li12Li5792.2(17)
I1Li1Li7255.0(3) Li4Li12Li5787.8(17)
I1Li1Li10354.6(3) Li47Li12Li1579(2)
I1Li1Li1564.7(14) Li47Li12Li15171(2)
I1Li1S41163.4(4) Li4Li12Li159(2)
S11Li1Li2114.2(4) Li4Li12Li157171(2)
S11Li1Li3150.6(3) Li4Li12S1183.1(15)
S11Li1Li7275.0(4) Li4Li12S1296.9(15)
S11Li1Li103144.1(4) Li47Li12S1196.9(15)
S11Li1Li1557.4(14) Li47Li12S1283.1(15)
S11Li1I192.0(3) Li47Li12S22131.0(15)
S11Li1S4177.6(3) Li4Li12S2249.0(15)
S3Li1Li251.9(3) Li47Li12S2149.0(15)
S3Li1Li31132.1(4) Li4Li12S21131.0(15)
S3Li1Li7248.7(3) Li47Li12S3130.8(15)
S3Li1Li103111.3(5) Li47Li12S3749.2(15)
S3Li1Li1549.2(12) Li4Li12S349.2(15)
S3Li1I1101.4(3) Li4Li12S37130.8(15)
S3Li1S1185.6(3) Li57Li12Li5180.0
S3Li1S4190.8(3) Li57Li12S21124.5(9)
S3Li1S51168.4(4) Li5Li12S2155.5(9)
S3Li1S789.8(3) Li5Li12S22124.5(9)
S41Li1Li258.9(3) Li57Li12S2255.5(9)
S41Li1Li3196.5(4) Li5Li12S37130.2(6)
S41Li1Li72132.0(4) Li5Li12S349.8(6)
S41Li1Li103130.9(4) Li57Li12S3130.2(6)
S41Li1Li15117.9(15) Li57Li12S3749.8(6)
S51Li1Li2119.7(4) Li15Li12Li5782.5(17)
S51Li1Li3151.2(3) Li157Li12Li5797.5(17)
S51Li1Li72141.4(4) Li157Li12Li582.5(17)
S51Li1Li10376.8(4) Li15Li12Li597.5(17)
S51Li1Li15137.5(12) Li157Li12Li15180.0
S51Li1I190.1(3) Li157Li12S1274.2(19)
S51Li1S1192.3(3) Li15Li12S1174.2(19)
S51Li1S4177.6(2) Li157Li12S11105.8(19)
S7Li1Li252.6(3) Li15Li12S12105.8(19)
S7Li1Li31137.6(4) Li15Li12S21129.1(17)
S7Li1Li72112.4(5) Li157Li12S22129.1(17)
S7Li1Li10350.8(3) Li157Li12S2150.9(17)
S7Li1Li15128.1(14) Li15Li12S2250.9(17)
S7Li1I1103.2(3) Li157Li12S3751.2(15)
S7Li1S11164.7(4) Li15Li12S351.2(15)
S7Li1S4187.9(3) Li15Li12S37128.8(15)
S7Li1S5189.3(3) Li157Li12S3128.8(15)
S3Li2S4194.0(4) S12Li12Li57116.8(7)
S3Li2S64101.0(3) S11Li12Li5763.2(7)
S3Li2S795.4(3) S12Li12Li563.2(7)
S64Li2S41104.5(4) S11Li12Li5116.8(7)
S64Li2S7156.9(5) S12Li12S11180.00(3)
S7Li2S4190.3(3) S12Li12S2198.41(3)
Li15Li3Li72105.5(5) S12Li12S2281.59(3)
Li15Li3Li103101.9(5) S11Li12S2298.41(3)
Li15Li3I1554.2(2) S11Li12S2181.59(3)
Li72Li3Li10390.8(6) S11Li12S3795.11(3)
Li72Li3I15134.5(5) S11Li12S384.89(3)
I1Li3Li15143.3(6) S12Li12S3784.89(3)
I16Li3Li15121.1(4) S12Li12S395.11(3)
I1Li3Li7256.8(4) S22Li12S21180.00(2)
I16Li3Li7277.3(4) S3Li12S2183.09(3)
I16Li3Li103137.0(5) S37Li12S2196.91(3)
I1Li3Li10352.0(4) S37Li12S2283.09(3)
I15Li3Li103130.4(5) S3Li12S2296.91(3)
I1Li3I1688.4(3) S37Li12S3180.0
I16Li3I1581.6(3) Li2Li13Li490.1(11)
I1Li3I15161.4(6) Li2Li13Li47110.9(13)
S1Li3Li1557.3(3) Li2Li13Li12100.7(11)
S1Li3Li7252.1(4) Li47Li13Li433.9(12)
S1Li3Li103117.3(6) Li5Li13Li2130(4)
S1Li3I1687.6(3) Li5Li13Li443(4)
S1Li3I1107.9(5) Li5Li13Li4743(5)
S1Li3I1587.4(3) Li5Li13Li6241(5)
S1Li3S5102.6(5) Li5Li13Li104132(4)
S5Li3Li1557.0(3) Li5Li13Li118138(6)
S5Li3Li72119.8(6) Li5Li13Li1240(4)
S5Li3Li10349.4(4) Li5Li13I1878(4)
S5Li3I1101.2(4) Li5Li13S2186(6)
S5Li3I16162.9(6) Li5Li13S379(4)
S5Li3I1585.2(3) Li5Li13S64164(7)
Si12Li4Li15788.2(16) Li62Li13Li2116(2)
Li47Li4Si1292.8(17) Li62Li13Li467(2)
Li47Li4Li568.0(16) Li62Li13Li4783(2)
Li47Li4Li5771.9(17) Li62Li13Li104118(2)
Li47Li4Li72177(2) Li62Li13Li118168(2)
Li47Li4Li1576.2(16) Li62Li13Li1274(2)
Li47Li4S1173.2(15) Li62Li13I1871.9(18)
Li47Li4S1261.5(15) Li62Li13S21127(3)
Li47Li4S22113.6(19) Li62Li13S375(2)
Li47Li4S3112.8(18) Li62Li13S64123(3)
Li57Li4Si1286.1(10) Li104Li13Li297.7(13)
Li5Li4Si1295.7(11) Li104Li13Li47132.5(17)
Li57Li4Li5139.9(14) Li104Li13Li4166.3(18)
Li5Li4Li15764.4(14) Li104Li13Li12149.6(17)
Li57Li4Li15775.6(14) Li118Li13Li273.8(12)
Li72Li4Si1284.2(10) Li118Li13Li47100.7(16)
Li72Li4Li5111.2(14) Li118Li13Li4121.5(17)
Li72Li4Li57108.8(13) Li118Li13Li10451.2(10)
Li72Li4Li157170.9(18) Li118Li13Li12111.9(17)
Li72Li4S11109.8(13) Li12Li13Li416.8(6)
Li72Li4S12115.5(12) Li12Li13Li4717.1(6)
Li72Li4S2264.8(9) I18Li13Li2147.8(16)
Li72Li4S368.0(10) I18Li13Li47100.9(13)
Li12Li4Si1292.8(17) I18Li13Li4120.3(15)
Li12Li4Li470.001(5) I18Li13Li10455.0(8)
Li12Li4Li568.0(16) I18Li13Li11896.0(13)
Li12Li4Li5771.9(17) I18Li13Li12111.4(13)
Li12Li4Li72177(2) S21Li13Li299.1(15)
Li12Li4Li15163(4) S21Li13Li4747.6(9)
Li12Li4Li1576.2(16) S21Li13Li475.4(12)
Li12Li4S1261.5(15) S21Li13Li10492.1(15)
Li12Li4S1173.2(15) S21Li13Li11853.5(11)
Li12Li4S22113.6(19) S21Li13Li1261.2(9)
Li12Li4S3112.8(18) S21Li13I1898.6(13)
Li15Li4Si12100(4) S21Li13S64109.3(18)
Li15Li4Li47163(4) S3Li13Li251.2(7)
Li15Li4Li5121(3) S3Li13Li4777.2(12)
Li15Li4Li5798(3) S3Li13Li445.1(9)
Li15Li4Li7220(3) S3Li13Li104146.5(18)
Li15Li4Li157170(3) S3Li13Li118117.3(17)
Li15Li4S12135(4) S3Li13Li1260.8(9)
Li15Li4S1190(4) S3Li13I18147(2)
Li15Li4S2270(3) S3Li13S21103.6(16)
Li15Li4S371(3) S3Li13S6497.5(14)
S11Li4Si12145.8(12) S64Li13Li250.3(7)
S12Li4Si1243.7(4) S64Li13Li4140.3(15)
S12Li4Li557.0(8) S64Li13Li47151.9(19)
S11Li4Li5760.1(10) S64Li13Li10449.1(8)
S11Li4Li5106.9(12) S64Li13Li11856.7(10)
S12Li4Li57103.1(12) S64Li13Li12149.6(16)
S12Li4Li15755.4(15) S64Li13I1898.3(13)
S11Li4Li15779.3(15) Li15Li14Li89107(5)
S11Li4S12134.7(14) Li15Li14Li93113(4)
S11Li4S22112.3(10) Li15Li14Li1312117(4)
S22Li4Si1244.5(4) Li15Li14I1566(3)
S22Li4Li5759.9(10) Li15Li14S564(3)
S22Li4Li5139.4(13) Li15Li14S69158(5)
S22Li4Li157112.6(16) Li8Li14Li15112(7)
S22Li4S1287.1(8) Li8Li14Li898(2)
S3Li4Si12118.5(10) Li8Li14Li9360(4)
S3Li4Li57153.8(13) Li89Li14Li9355(2)
S3Li4Li552.2(8) Li89Li14Li1312116(4)
S3Li4Li157111.7(14) Li8Li14Li1312117(6)
S3Li4S12101.3(9) Li8Li14I15155(7)
S3Li4S1195.7(9) Li8Li14S566(5)
S3Li4S22130.9(14) Li8Li14S6971(4)
Li47Li5Li440.1(14) Li8Li14S7581(5)
Li4Li5Li781.0(11) Li93Li14Li131266(2)
Li47Li5Li7100.5(12) Li109Li14Li15120(9)
Li47Li5Li15721.1(13) Li109Li14Li89129(8)
Li4Li5Li15760.8(17) Li109Li14Li8122(9)
Li47Li5I18116.1(12) Li109Li14Li93116(8)
Li62Li5Li494(2) Li109Li14Li131259(6)
Li62Li5Li47120(3) Li109Li14I1575(7)
Li62Li5Li721(2) Li109Li14S5162(9)
Li62Li5Li12108(3) Li109Li14S6970(6)
Li62Li5Li157126(3) Li109Li14S7595(8)
Li62Li5I1878(2) I15Li14Li89147(5)
Li62Li5S1272(2) I15Li14Li9397(3)
Li62Li5S21171(3) I15Li14Li131253(2)
Li62Li5S383(2) S5Li14Li8958(3)
Li7Li5Li157105.0(15) S5Li14Li9352(2)
Li12Li5Li4720.3(7) S5Li14Li1312104(4)
Li12Li5Li419.8(7) S5Li14I1593(4)
Li12Li5Li790.7(10) S69Li14Li8973(3)
Li12Li5Li15741.1(14) S69Li14Li9349(2)
Li12Li5I18132.2(12) S69Li14Li131249(2)
Li13Li5Li4127(4) S69Li14I15102(4)
Li13Li5Li47127(6) S69Li14S5101(4)
Li13Li5Li62110(7) S75Li14Li1568(3)
Li13Li5Li7131(6) S75Li14Li8985(4)
Li13Li5Li12130(5) S75Li14Li93139(6)
Li13Li5Li157123(6) S75Li14Li1312153(6)
Li13Li5I1887(4) S75Li14I15118(5)
Li13Li5S12175(5) S75Li14S5102(5)
Li13Li5S2177(6) S75Li14S69133(5)
Li13Li5S383(4) Li1Li15Li4797(2)
I18Li5Li4144.8(13) Li1Li15Li57107(2)
I18Li5Li780.1(10) Li1Li15Li6137(3)
I18Li5Li15796.2(15) Li1Li15I157.4(14)
S12Li5Li4752.4(8) Li4Li15Li1104(4)
S12Li5Li456.7(8) Li4Li15Li4710(3)
S12Li5Li751.1(7) Li47Li15Li5754.8(14)
S12Li5Li1251.9(6) Li4Li15Li5761(3)
S12Li5Li15753.9(14) Li4Li15Li6114(4)
S12Li5I1888.5(9) Li4Li15Li128(2)
S12Li5S21100.0(12) Li47Li15I1141(2)
S21Li5Li484.1(12) Li4Li15I1151(5)
S21Li5Li4753.6(9) Li4Li15S1164(3)
S21Li5Li7151.0(12) Li4Li15S2283(4)
S21Li5Li1268.4(9) Li4Li15S381(3)
S21Li5Li15746.1(14) Li6Li15Li47123(2)
S21Li5I1898.7(11) Li6Li15Li57108(2)
S3Li5Li4788.7(12) Li6Li15I192(2)
S3Li5Li453.3(9) Li72Li15Li1104(5)
S3Li5Li788.1(12) Li72Li15Li4139(7)
S3Li5Li1270.5(8) Li72Li15Li47150(5)
S3Li5Li157109.3(17) Li72Li15Li57134(4)
S3Li5I18154.0(17) Li72Li15Li633(3)
S3Li5S12102.0(12) Li72Li15Li12147(5)
S3Li5S21102.7(13) Li72Li15I169(4)
Si12Li6Li4279.5(8) Li72Li15S11156(6)
Si12Li6Li45112.5(9) Li72Li15S2284(4)
Si12Li6Li12596.9(7) Li72Li15S390(4)
Si12Li6Li1567.0(16) Li12Li15Li199(3)
Li42Li6Li4534.2(12) Li12Li15Li472.8(8)
Li42Li6Li12517.9(6) Li12Li15Li5756.4(16)
Li52Li6Si12115(3) Li12Li15Li6121(3)
Li52Li6Li4545(2) Li12Li15I1144(3)
Li52Li6Li4267(2) Li12Li15S1156.5(17)
Li52Li6Li72150(3) Li12Li15S2285(3)
Li52Li6Li12554(2) Li12Li15S383(2)
Li52Li6Li13229(3) I1Li15Li57101.3(17)
Li52Li6Li15160(3) S11Li15Li157.3(14)
Li52Li6I1681(2) S11Li15Li4753.7(15)
Li52Li6S185(2) S11Li15Li5752.6(14)
Li52Li6S22147(3) S11Li15Li6160(2)
Li52Li6S3273(2) S11Li15I187.4(19)
Li72Li6Si1280.8(10) S22Li15Li1155(3)
Li72Li6Li45106.2(11) S22Li15Li4785(2)
Li72Li6Li4292.8(11) S22Li15Li5754.9(15)
Li72Li6Li125100.2(10) S22Li15Li653.8(15)
Li72Li6Li1514.8(14) S22Li15I1106(2)
Li72Li6I1699.5(12) S22Li15S11108(2)
Li72Li6S164.4(10) S3Li15Li158.0(15)
Li72Li6S2261.5(10) S3Li15Li4784(2)
Li72Li6S32111.5(11) S3Li15Li57135(3)
Li125Li6Li4516.2(6) S3Li15Li6108(2)
Li132Li6Si12102(2) S3Li15I1102(2)
Li132Li6Li4573(2) S3Li15S1191(2)
Li132Li6Li4287(2) S3Li15S22146(3)
Li132Li6Li72178(2) Li1I1Li313131.2(3)
Li132Li6Li12579(2) Li1I1Li3158.8(3)
Li132Li6Li15168(3) Li1I1Li7270.3(4)
Li132Li6I1678.6(18) Li1I1Li1311123.9(9)
Li132Li6S1114(3) Li1I1Li1558.0(12)
Li132Li6S22120(2) Li3I1Li1103.3(4)
Li132Li6S3270(2) Li3I1Li31399.1(4)
Li15Li6Li45115.6(14) Li3I1Li31161.4(6)
Li15Li6Li4295.1(14) Li313I1Li3190.9(3)
Li15Li6Li125106.3(13) Li3I1Li7266.9(5)
I16Li6Si12146.5(11) Li3I1Li131190.1(11)
I16Li6Li42133.6(12) Li3I1Li1586.4(13)
I16Li6Li4599.7(10) Li313I1Li1581.2(11)
I16Li6Li125115.8(9) Li511I1Li1136.9(7)
I16Li6Li15107.8(18) Li511I1Li31383.7(7)
S1Li6Si12117.6(10) Li511I1Li31104.1(9)
S1Li6Li4254.3(7) Li511I1Li392.6(9)
S1Li6Li4544.5(6) Li511I1Li72151.0(8)
S1Li6Li12547.0(5) Li511I1Li131114.8(8)
S1Li6Li1577.1(15) Li511I1Li15164.5(13)
S1Li6I1691.7(8) Li613I1Li1129.6(6)
S1Li6S22124.9(15) Li613I1Li3184.5(8)
S22Li6Si1243.9(4) Li613I1Li3113.0(8)
S22Li6Li42118.4(11) Li613I1Li31376.9(7)
S22Li6Li45152.2(11) Li613I1Li51120.8(10)
S22Li6Li125136.2(9) Li613I1Li72156.3(7)
S22Li6Li1547.9(14) Li613I1Li131129.5(13)
S22Li6I16106.7(10) Li613I1Li14193(3)
S32Li6Si1244.0(4) Li613I1Li15152.6(14)
S32Li6Li4574.0(9) Li72I1Li31379.8(4)
S32Li6Li4249.1(7) Li72I1Li3199.8(5)
S32Li6Li12561.5(6) Li72I1Li1311156.2(11)
S32Li6Li15102.1(16) Li72I1Li1520.2(12)
S32Li6I16148.9(16) Li103I1Li167.0(5)
S32Li6S1103.0(9) Li103I1Li313161.7(5)
S32Li6S2287.3(8) Li103I1Li372.9(5)
Si12Li7Li1281.0(4) Li103I1Li31101.6(5)
Si12Li7Li3277.0(5) Li103I1Li51180.4(8)
Si12Li7Li587.8(7) Li103I1Li61391.0(8)
Si12Li7Li12596.8(5) Li103I1Li72110.6(4)
Li32Li7Li1287.8(5) Li103I1Li131165.7(10)
Li32Li7Li576.0(7) Li103I1Li14122(3)
Li42Li7Si1297.0(9) Li103I1Li15114.0(11)
Li42Li7Li1273.0(9) Li1311I1Li31398.6(9)
Li42Li7Li32160.6(11) Li1311I1Li31104.0(11)
Li42Li7Li5122.6(11) Li1311I1Li15176.4(16)
Li42Li7Li62117.3(12) Li141I1Li151(2)
Li42Li7Li1251.0(7) Li141I1Li392(3)
Li42Li7I12111.6(10) Li141I1Li3180(3)
Li42Li7S12134.7(10) Li141I1Li313167(3)
Li42Li7S265.1(9) Li141I1Li51189(2)
Li42Li7S3261.9(9) Li141I1Li72111(2)
Li5Li7Li12162.1(9) Li141I1Li131175(3)
Li62Li7Si1296.2(9) Li141I1Li15106(3)
Li62Li7Li12169.6(10) Li15I1Li3179.6(13)
Li62Li7Li3281.8(9) Si1S1Li1589.41(19)
Li62Li7Li59.3(10) Si1S1Li3116.3(3)
Li62Li7Li125116.4(9) Si1S1Li4276.2(6)
Li62Li7I12118.5(10) Si1S1Li45106.3(7)
Li62Li7S1262.7(9) Si1S1Li52131.5(7)
Li62Li7S264.8(8) Si1S1Li6119.3(6)
Li62Li7S32132.5(10) Si1S1Li7281.4(4)
Li125Li7Li1274.0(5) Si1S1Li12590.66(5)
Li125Li7Li32161.5(7) Si1S1Li155122.2(13)
Li125Li7Li5121.6(7) Li15S1Li15565.3(15)
Li152Li7Si12107(3) Li3S1Li1572.1(3)
Li152Li7Li1258(4) Li3S1Li42166.3(6)
Li152Li7Li32143(4) Li3S1Li52100.0(7)
Li152Li7Li4221(4) Li3S1Li693.4(7)
Li152Li7Li5140(4) Li3S1Li7278.4(5)
Li152Li7Li62132(4) Li3S1Li155104.2(16)
Li152Li7Li12522(4) Li42S1Li15115.4(7)
Li152Li7I1290(4) Li45S1Li1582.5(8)
Li152Li7S12149(3) Li45S1Li3129.2(8)
Li152Li7S270(3) Li45S1Li4245.3(14)
Li152Li7S3265(3) Li45S1Li5267.5(11)
I12Li7Si12112.8(5) Li42S1Li5266.4(8)
I12Li7Li1254.7(3) Li45S1Li688.5(11)
I12Li7Li3256.2(4) Li45S1Li72136.3(8)
I12Li7Li5118.8(8) Li45S1Li15525.6(16)
I12Li7Li125112.6(6) Li42S1Li15570.9(19)
S12Li7Si1242.8(2) Li52S1Li15133.8(9)
S12Li7Li12109.9(5) Li52S1Li15573.5(17)
S12Li7Li3249.5(4) Li6S1Li15151.3(7)
S12Li7Li553.5(7) Li6S1Li4274.7(9)
S12Li7Li125134.2(6) Li6S1Li5222.6(10)
S12Li7I12104.7(6) Li6S1Li7252.9(10)
S2Li7Si12138.3(6) Li6S1Li15596.0(16)
S2Li7Li12123.5(7) Li72S1Li15141.1(4)
S2Li7Li32130.9(8) Li72S1Li4299.1(8)
S2Li7Li573.9(7) Li72S1Li5275.4(10)
S2Li7Li12564.7(4) Li72S1Li155148.8(13)
S2Li7I12108.9(5) Li125S1Li15100.1(2)
S2Li7S12126.4(7) Li125S1Li3151.2(3)
S2Li7S32125.3(8) Li125S1Li4221.6(7)
S32Li7Si1242.7(2) Li125S1Li4523.7(8)
S32Li7Li1250.0(4) Li125S1Li5264.8(7)
S32Li7Li32103.8(6) Li125S1Li680.6(8)
S32Li7Li5126.3(8) Li125S1Li72117.6(4)
S32Li7Li12562.1(5) Li125S1Li15549.3(16)
S32Li7I12102.2(6) Si1S2Li4279.9(6)
S32Li7S1285.1(5) Si1S2Li55111.0(6)
Si29Li8Li11982.6(8) Si1S2Li6279.1(6)
Li89Li8Si2991.1(18) Si1S2Li797.3(4)
Li89Li8Li9375.6(18) Si1S2Li91090.4(5)
Li89Li8Li9578(2) Si1S2Li1114101.9(7)
Li89Li8Li109169(2) Si1S2Li12573.99(4)
Li89Li8Li11988(2) Si1S2Li135110.4(8)
Li89Li8Li14162(5) Si1S2Li15297.6(16)
Li89Li8Li14910(3) Li42S2Li5566.4(10)
Li89Li8S5965.3(17) Li42S2Li6295.6(10)
Li89Li8S584.7(19) Li42S2Li910164.0(10)
Li89Li8S69110(2) Li42S2Li1114152.1(11)
Li89Li8S75127(2) Li42S2Li12517.4(8)
Li93Li8Si2985.1(7) Li42S2Li13581.6(12)
Li95Li8Si2995.5(8) Li55S2Li12556.1(7)
Li95Li8Li93154.0(11) Li62S2Li55156.2(11)
Li95Li8Li11915.8(6) Li62S2Li91095.0(10)
Li93Li8Li119159.1(11) Li62S2Li1114112.1(11)
Li109Li8Si2979.7(8) Li62S2Li125109.9(7)
Li109Li8Li95107.5(11) Li62S2Li135169.3(12)
Li109Li8Li9398.2(10) Li7S2Li4250.0(9)
Li109Li8Li11996.2(10) Li7S2Li55102.9(8)
Li109Li8Li149164(3) Li7S2Li6253.6(10)
Li109Li8S599.7(10) Li7S2Li910144.9(8)
Li109Li8S59109.9(10) Li7S2Li1114153.3(7)
Li109Li8S6959.3(7) Li7S2Li12567.4(5)
Li109Li8S7562.5(8) Li7S2Li135118.5(11)
Li149Li8Si2984(3) Li910S2Li55106.1(9)
Li14Li8Si29102(5) Li910S2Li125146.9(6)
Li14Li8Li95112(4) Li1114S2Li5587.5(11)
Li149Li8Li9573(2) Li1114S2Li91019.2(8)
Li14Li8Li9393(4) Li1114S2Li125136.0(7)
Li149Li8Li9382(2) Li1114S2Li13571.7(13)
Li14Li8Li10923(4) Li135S2Li5516.2(9)
Li14Li8Li119106(4) Li135S2Li91090.1(12)
Li149Li8Li11980(2) Li135S2Li12569.4(10)
Li14Li8Li149172(2) Li152S2Li4227.7(19)
Li14Li8S578(5) Li152S2Li5579.0(19)
Li14Li8S59132(5) Li152S2Li6278.3(19)
Li14Li8S6973(4) Li152S2Li725.5(17)
Li14Li8S7560(4) Li152S2Li910168(2)
S59Li8Si2942.6(3) Li152S2Li1114159.3(17)
S5Li8Si29144.8(9) Li152S2Li12544.6(19)
S5Li8Li9360.0(7) Li152S2Li13595(2)
S59Li8Li93109.4(8) Si1S3Li1125.3(2)
S5Li8Li95117.6(10) Si1S3Li297.2(3)
S59Li8Li9558.4(7) Si1S3Li4120.7(7)
S5Li8Li119131.9(11) Si1S3Li5104.5(10)
S59Li8Li11951.1(7) Si1S3Li6281.3(8)
S59Li8Li14956(2) Si1S3Li7282.4(4)
S5Li8Li14994(3) Si1S3Li12131.17(5)
S5Li8S59149.9(12) Si1S3Li13104.9(12)
S5Li8S69106.4(8) Si1S3Li15106.6(18)
S5Li8S7598.4(7) Li1S3Li1288.7(2)
S69Li8Si2943.1(3) Li2S3Li172.1(3)
S69Li8Li9356.3(7) Li2S3Li62107.0(8)
S69Li8Li95135.8(10) Li2S3Li72147.1(4)
S69Li8Li119120.7(10) Li2S3Li12128.6(3)
S69Li8Li149109(3) Li4S3Li185.2(7)
S69Li8S5985.2(6) Li4S3Li2142.1(7)
S75Li8Si29111.8(8) Li4S3Li6280.2(10)
S75Li8Li93149.7(11) Li4S3Li7250.1(9)
S75Li8Li9552.9(6) Li4S3Li1218.0(8)
S75Li8Li11951.2(6) Li5S3Li1129.6(10)
S75Li8Li149124(3) Li5S3Li296.7(9)
S75Li8S5999.6(7) Li5S3Li474.5(11)
S75Li8S69119.4(11) Li5S3Li6224.3(11)
Li81Li9Li8326.0(11) Li5S3Li72115.3(9)
Li83Li9Li1090.7(8) Li5S3Li1259.8(8)
Li81Li9Li1080.3(8) Li5S3Li1317.9(10)
Li83Li9Li14327(2) Li62S3Li1153.4(8)
Li81Li9Li14353(2) Li62S3Li72105.4(9)
Li83Li9S44147.4(10) Li62S3Li1270.9(7)
Li81Li9S44139.2(9) Li72S3Li181.3(4)
Li10Li9Li14395(2) Li72S3Li1268.1(4)
Li113Li9Li8197(2) Li13S3Li1123.9(13)
Li113Li9Li83111(3) Li13S3Li278.9(11)
Li113Li9Li1021(2) Li13S3Li489.8(13)
Li113Li9Li143116(3) Li13S3Li6234.8(15)
Li113Li9S2477(2) Li13S3Li72133.1(11)
Li113Li9S4497(3) Li13S3Li1273.4(11)
Li113Li9S5368(2) Li15S3Li172.8(18)
Li113Li9S61163(3) Li15S3Li2144.6(18)
Li113Li9S784(2) Li15S3Li428.5(19)
S24Li9Li81147.4(11) Li15S3Li5102(2)
S24Li9Li83127.1(10) Li15S3Li62102(2)
S24Li9Li1084.3(7) Li15S3Li7225.0(18)
S24Li9Li143101(2) Li15S3Li1246(2)
S24Li9S4473.3(6) Li15S3Li13118(2)
S24Li9S5393.3(7) Si1S4Li1582.27(19)
S24Li9S61107.2(8) Si1S4Li25111.8(2)
S44Li9Li10118.7(9) Si1S4Li91079.6(4)
S44Li9Li143144(2) Si2S4Si1111.72(5)
S53Li9Li8349.8(6) Si2S4Li1582.09(19)
S53Li9Li8155.4(6) Si2S4Li25117.04(19)
S53Li9Li1047.5(5) Si2S4Li910142.0(5)
S53Li9Li14348(2) Li15S4Li910135.9(5)
S53Li9S44162.8(10) Li25S4Li1561.6(3)
S61Li9Li8353.1(7) Li25S4Li91088.8(6)
S61Li9Li8170.8(8) Si2S5Li1589.20(19)
S61Li9Li10142.0(10) Si2S5Li3117.2(4)
S61Li9Li14347(2) Si2S5Li8979.1(5)
S61Li9S4499.3(8) Si2S5Li895.6(6)
S61Li9S5395.0(9) Si2S5Li93132.3(5)
S7Li9Li8153.8(7) Si2S5Li10377.7(4)
S7Li9Li8378.1(8) Si2S5Li11123.5(6)
S7Li9Li1085.0(7) Si2S5Li14115(3)
S7Li9Li143105(2) Li15S5Li93131.0(6)
S7Li9S24152.7(12) Li3S5Li1571.8(3)
S7Li9S4490.1(8) Li3S5Li89163.5(7)
S7Li9S5397.9(7) Li3S5Li93101.4(5)
S7Li9S6196.7(8) Li3S5Li10383.0(4)
Si23Li10Li1384.9(4) Li3S5Li1196.4(7)
Si23Li10Li3376.9(5) Li3S5Li14102(3)
Si23Li10Li987.9(7) Li89S5Li15107.3(5)
Si23Li10Li1310150.6(13) Li8S5Li1582.7(6)
Li13Li10Li3388.5(5) Li8S5Li3137.2(7)
Li13Li10Li9161.7(8) Li8S5Li8930.1(12)
Li33Li10Li973.4(7) Li8S5Li9370.3(7)
Li89Li10Si2398.2(8) Li89S5Li9366.2(7)
Li89Li10Li1375.1(8) Li8S5Li103133.1(7)
Li89Li10Li33163.3(10) Li8S5Li1186.1(10)
Li89Li10Li9122.7(9) Li8S5Li1436(3)
Li89Li10Li113119.7(10) Li103S5Li15142.3(4)
Li89Li10Li1310109.6(12) Li103S5Li89104.6(7)
Li89Li10I13115.9(10) Li103S5Li9380.4(7)
Li89Li10S53136.8(9) Li103S5Li14161(3)
Li89Li10S664.6(7) Li11S5Li15146.3(7)
Li89Li10S7361.8(7) Li11S5Li8975.1(8)
Li113Li10Si2394.6(9) Li11S5Li9318.5(8)
Li113Li10Li13165.0(9) Li11S5Li10362.1(10)
Li113Li10Li3376.8(8) Li11S5Li1499(3)
Li113Li10Li96.9(8) Li14S5Li1555(3)
Li113Li10Li131063.5(12) Li14S5Li8966(3)
Li113Li10I13109.3(8) Li14S5Li9380(3)
Li1310Li10Li13111.0(11) Si2S6Li21095.3(2)
Li1310Li10Li3378.9(10) Si2S6Li8982.0(5)
Li1310Li10Li969.2(11) Si2S6Li95118.7(5)
Li149Li10Si23104(6) Si2S6Li10101.2(4)
Li149Li10Li1343(7) Si2S6Li11381.3(6)
Li149Li10Li33130(7) Si2S6Li1310148.1(12)
Li149Li10Li8935(7) Si2S6Li149105(3)
Li149Li10Li9155(7) Li210S6Li89159.1(7)
Li149Li10Li113150(7) Li210S6Li9593.1(6)
Li149Li10Li1310104(6) Li210S6Li11390.1(6)
Li149Li10I1383(6) Li210S6Li131074.3(8)
Li149Li10S53147(7) Li210S6Li149158(3)
Li149Li10S685(7) Li89S6Li9570.6(7)
Li149Li10S7360(6) Li89S6Li113109.9(8)
I13Li10Si23116.9(5) Li89S6Li1310118.0(10)
I13Li10Li1358.4(4) Li89S6Li14936(3)
I13Li10Li3355.1(4) Li95S6Li113159.3(7)
I13Li10Li9111.0(7) Li95S6Li131092.3(12)
I13Li10Li131059.3(9) Li10S6Li210144.0(6)
S53Li10Si2344.3(3) Li10S6Li8956.1(8)
S53Li10Li13113.0(5) Li10S6Li95106.2(8)
S53Li10Li3347.6(4) Li10S6Li11361.6(8)
S53Li10Li952.0(6) Li10S6Li131074.9(9)
S53Li10Li11358.8(8) Li10S6Li14925(3)
S53Li10Li1310106.4(12) Li1310S6Li11368.9(13)
S53Li10I13102.6(6) Li149S6Li9583(3)
S6Li10Si23134.6(7) Li149S6Li11386(3)
S6Li10Li13125.0(9) Li149S6Li131085(3)
S6Li10Li33129.9(8) Si2S7Li1121.7(2)
S6Li10Li971.1(7) Si2S7Li299.5(3)
S6Li10Li11364.9(7) Si2S7Li81121.9(6)
S6Li10Li131056.0(8) Si2S7Li9105.7(7)
S6Li10I13108.2(6) Si2S7Li10379.4(5)
S6Li10S53121.9(9) Si2S7Li11386.4(8)
S6Li10S73123.7(8) Si2S7Li141104(4)
S73Li10Si2344.4(3) Li2S7Li171.4(3)
S73Li10Li1353.5(4) Li2S7Li103140.3(4)
S73Li10Li33105.9(6) Li2S7Li113108.8(6)
S73Li10Li9128.1(8) Li81S7Li183.6(5)
S73Li10Li113133.5(10) Li81S7Li2138.6(6)
S73Li10Li1310162.7(14) Li81S7Li10355.6(8)
S73Li10I13109.4(7) Li81S7Li11378.7(8)
S73Li10S5388.3(5) Li9S7Li1132.5(7)
Si23Li11Li8101.4(8) Li9S7Li299.7(6)
Li89Li11Si2378.3(7) Li9S7Li8173.3(9)
Li89Li11Li823.1(10) Li9S7Li103119.0(7)
Li93Li11Si23115(3) Li9S7Li11320.1(8)
Li93Li11Li855(2) Li103S7Li175.7(5)
Li93Li11Li8967(2) Li103S7Li113110.7(7)
Li93Li11Li103152(3) Li113S7Li1151.8(8)
Li93Li11Li1311136(3) Li141S7Li161(3)
Li93Li11S21284(2) Li141S7Li2133(3)
Li93Li11S593(3) Li141S7Li8139(4)
Li93Li11S63150(3) Li141S7Li9112(4)
Li93Li11S7376(3) Li141S7Li10325(4)
Li103Li11Si2373.3(8) Li141S7Li113113(3)
Li103Li11Li897.8(8)     

1+X,1+Y,+Z; 21-X,1-Y,1-Z; 31-X,1-Y,-Z; 43/2-X,1/2+Y,1/2-Z; 5+X,-1+Y,+Z; 61/2-X,-1/2+Y,1/2-Z; 71-X,2-Y,1-Z; 81/2+X,3/2-Y,1/2+Z; 91-X,-Y,-Z; 103/2-X,-1/2+Y,1/2-Z; 11-1/2+X,3/2-Y,-1/2+Z; 12-1/2+X,1/2-Y,-1/2+Z; 131/2-X,1/2+Y,1/2-Z; 141/2+X,1/2-Y,1/2+Z

 

Table 6 Torsion Angles for Li7Si2S7I_330K.
ABCDAngle/˚ ABCDAngle/˚
Si11Li4Li12Li595.1(10) Li12Li4Li15S3105(14)
Si11Li4Li12Li52-84.9(10) Li12Li5Li13Li2-52(10)
Si11Li4Li12Li15-139(14) Li12Li5Li13Li4-25.2(19)
Si11Li4Li12S13-148.2(7) Li12Li5Li13Li4226(3)
Si11Li4Li12S1131.8(7) Li12Li5Li13Li61-137(7)
Si11Li4Li12S23139.2(10) Li12Li5Li13Li108137(4)
Si11Li4Li12S21-40.8(10) Li12Li5Li13Li11961(8)
Si11Li4Li12S3122.6(17) Li12Li5Li13I19147(5)
Si11Li4Li12S32-57.4(17) Li12Li5Li13S2347(5)
Si11Li4Li15Li1-170.6(15) Li12Li5Li13S3-57(5)
Si11Li4Li15Li42138(14) Li12Li5Li13S68-135(14)
Si11Li4Li15Li5287.3(14) Li152Li4Li12Li554(14)
Si11Li4Li15Li6-11(3) Li152Li4Li12Li52-126(14)
Si11Li4Li15Li71-38(9) Li15Li4Li12Li5-126(14)
Si11Li4Li15Li12138(14) Li15Li4Li12Li5254(14)
Si11Li4Li15I1144(7) Li152Li4Li12Li15180.00(9)
Si11Li4Li15S13147.2(14) Li152Li4Li12S11-10(14)
Si11Li4Li15S2133.5(17) Li152Li4Li12S13170(14)
Si11Li4Li15S3-116.9(14) Li15Li4Li12S11170(14)
Si24Li8Li14Li15170(4) Li15Li4Li12S13-10(14)
Si24Li8Li14Li84-135(17) Li152Li4Li12S21-82(14)
Si24Li8Li14Li96-85.7(12) Li15Li4Li12S23-82(14)
Si24Li8Li14Li10418(11) Li152Li4Li12S2398(14)
Si24Li8Li14Li137-50(5) Li15Li4Li12S2198(14)
Si24Li8Li14I15-110(15) Li15Li4Li12S3281(14)
Si24Li8Li14S5-144.0(10) Li152Li4Li12S381(14)
Si24Li8Li14S64-32(2) Li15Li4Li12S3-99(14)
Si24Li8Li14S75109(3) Li152Li4Li12S32-99(14)
Li42Li4Li12Li575(19) Li152Li4Li15Li151(15)
Li42Li4Li12Li52-105(19) Li152Li4Li15Li420.00(7)
Li42Li4Li12Li15-158(24) Li152Li4Li15Li52-51(13)
Li42Li4Li12S13-168(19) Li152Li4Li15Li6-149(12)
Li42Li4Li12S1112(19) Li152Li4Li15Li71-176(8)
Li42Li4Li12S21-61(19) Li152Li4Li15Li120.00(11)
Li42Li4Li12S23119(19) Li152Li4Li15I16(21)
Li42Li4Li12S32-77(20) Li152Li4Li15S139(13)
Li42Li4Li12S3103(20) Li152Li4Li15S21-104(14)
Li42Li4Li15Li151(15) Li152Li4Li15S3105(14)
Li42Li4Li15Li52-51(13) Li152Li5Li13Li2-103(6)
Li42Li4Li15Li6-149(12) Li152Li5Li13Li4-77(6)
Li42Li4Li15Li71-176(8) Li152Li5Li13Li42-26(3)
Li42Li4Li15Li120.00(11) Li152Li5Li13Li61171(6)
Li42Li4Li15I16(21) Li152Li5Li13Li10885(8)
Li42Li4Li15S139(13) Li152Li5Li13Li11910(9)
Li42Li4Li15S21-104(14) Li152Li5Li13Li12-51(5)
Li42Li4Li15S3105(14) Li152Li5Li13I1995(4)
Li4Li5Li13Li2-26(10) Li152Li5Li13S23-4(4)
Li42Li5Li13Li2-77(8) Li152Li5Li13S3-109(4)
Li4Li5Li13Li4251(4) Li152Li5Li13S68174(13)
Li42Li5Li13Li4-51(4) I19Li5Li13Li2162(6)
Li4Li5Li13Li61-112(7) I19Li5Li13Li4-172(5)
Li42Li5Li13Li61-163(6) I19Li5Li13Li42-121(4)
Li42Li5Li13Li108111(6) I19Li5Li13Li6176(3)
Li4Li5Li13Li108162(3) I19Li5Li13Li108-10(7)
Li42Li5Li13Li11935(8) I19Li5Li13Li119-86(6)
Li4Li5Li13Li11986(7) I19Li5Li13Li12-147(5)
Li4Li5Li13Li1225.2(19) I19Li5Li13S23-99.6(9)
Li42Li5Li13Li12-26(3) I19Li5Li13S3155.7(13)
Li42Li5Li13I19121(4) I19Li5Li13S6878(16)
Li4Li5Li13I19172(5) S13Li4Li12Li5263.3(8)
Li42Li5Li13S2321(4) S13Li4Li12Li5-116.7(8)
Li4Li5Li13S2372(5) S11Li4Li12Li52-116.7(8)
Li4Li5Li13S3-32(5) S11Li4Li12Li563.3(8)
Li42Li5Li13S3-83(4) S11Li4Li12Li15-170(14)
Li4Li5Li13S68-110(16) S13Li4Li12Li1510(14)
Li42Li5Li13S68-161(13) S13Li4Li12S11180.000(7)
Li52Li4Li12Li5180.001(6) S11Li4Li12S13180.000(7)
Li5Li4Li12Li52179.999(5) S13Li4Li12S23-72.5(14)
Li5Li4Li12Li15126(14) S11Li4Li12S23107.5(14)
Li52Li4Li12Li15-54(14) S11Li4Li12S21-72.5(14)
Li5Li4Li12S13116.7(8) S13Li4Li12S21107.5(14)
Li52Li4Li12S11116.7(8) S13Li4Li12S3-89.2(13)
Li52Li4Li12S13-63.3(8) S11Li4Li12S32-89.2(13)
Li5Li4Li12S11-63.3(8) S11Li4Li12S390.8(13)
Li5Li4Li12S2344.2(15) S13Li4Li12S3290.8(13)
Li5Li4Li12S21-135.8(15) S11Li4Li15Li1-141(3)
Li52Li4Li12S23-135.8(15) S13Li4Li15Li142(2)
Li52Li4Li12S2144.2(15) S11Li4Li15Li42168(17)
Li5Li4Li12S32-152.5(16) S13Li4Li15Li42-9(13)
Li5Li4Li12S327.5(16) S11Li4Li15Li52117(4)
Li52Li4Li12S3-152.5(16) S13Li4Li15Li52-59.8(12)
Li52Li4Li12S3227.5(16) S13Li4Li15Li6-158(2)
Li52Li4Li15Li1102(2) S11Li4Li15Li619(6)
Li5Li4Li15Li1-68(4) S11Li4Li15Li71-8(12)
Li52Li4Li15Li4251(13) S13Li4Li15Li71174(8)
Li5Li4Li15Li42-119(15) S13Li4Li15Li12-9(13)
Li5Li4Li15Li52-170(3) S11Li4Li15Li12168(17)
Li52Li4Li15Li6-98(3) S11Li4Li15I1174(5)
Li5Li4Li15Li692(4) S13Li4Li15I1-3(8)
Li5Li4Li15Li7164(10) S11Li4Li15S13177(4)
Li52Li4Li15Li71-126(8) S13Li4Li15S21-113.7(14)
Li52Li4Li15Li1251(13) S11Li4Li15S2164(4)
Li5Li4Li15Li12-119(15) S11Li4Li15S3-87(4)
Li5Li4Li15I1-113(7) S13Li4Li15S395.9(14)
Li52Li4Li15I157(8) S21Li4Li12Li5135.8(15)
Li52Li4Li15S1359.8(12) S21Li4Li12Li52-44.2(15)
Li5Li4Li15S13-110(3) S21Li4Li12Li15-98(14)
Li52Li4Li15S21-53.8(19) S21Li4Li12S13-107.5(14)
Li5Li4Li15S21136(2) S21Li4Li12S1172.5(14)
Li52Li4Li15S3155.7(14) S21Li4Li12S23180.0
Li5Li4Li15S3-14(4) S21Li4Li12S32-17(3)
Li61Li5Li13Li286(7) S21Li4Li12S3163(3)
Li61Li5Li13Li42163(6) S21Li4Li15Li1156(3)
Li61Li5Li13Li4112(7) S21Li4Li15Li42104(14)
Li61Li5Li13Li108-86(7) S21Li4Li15Li5253.8(19)
Li61Li5Li13Li119-162(4) S21Li4Li15Li6-45(2)
Li61Li5Li13Li12137(7) S21Li4Li15Li71-72(8)
Li61Li5Li13I19-76(3) S21Li4Li15Li12104(14)
Li61Li5Li13S23-176(3) S21Li4Li15I1111(8)
Li61Li5Li13S380(3) S21Li4Li15S13113.7(14)
Li61Li5Li13S682(19) S21Li4Li15S3-150(2)
Li71Li4Li15Li1-132(10) S23Li5Li13Li2-99(6)
Li71Li4Li15Li42176(8) S23Li5Li13Li4-72(5)
Li71Li4Li15Li52126(8) S23Li5Li13Li42-21(4)
Li71Li4Li15Li627(7) S23Li5Li13Li61176(3)
Li71Li4Li15Li12176(8) S23Li5Li13Li10890(6)
Li71Li4Li15I1-177(16) S23Li5Li13Li11914(5)
Li71Li4Li15S13-174(8) S23Li5Li13Li12-47(5)
Li71Li4Li15S2172(8) S23Li5Li13I1999.6(9)
Li71Li4Li15S3-79(8) S23Li5Li13S3-104.6(10)
Li7Li5Li13Li287(7) S23Li5Li13S68178(17)
Li7Li5Li13Li42165(7) S3Li4Li12Li52152.5(16)
Li7Li5Li13Li4114(7) S3Li4Li12Li5-27.5(16)
Li7Li5Li13Li612(2) S3Li4Li12Li1599(14)
Li7Li5Li13Li108-84(8) S3Li4Li12S11-90.8(13)
Li7Li5Li13Li119-160(3) S3Li4Li12S1389.2(13)
Li7Li5Li13Li12139(8) S3Li4Li12S2317(3)
Li7Li5Li13I19-74(4) S3Li4Li12S21-163(3)
Li7Li5Li13S23-174(4) S3Li4Li12S32180.0
Li7Li5Li13S382(4) S3Li4Li15Li1-53.7(16)
Li7Li5Li13S684(20) S3Li4Li15Li42-105(14)
Li84Li8Li14Li15-54(19) S3Li4Li15Li52-155.7(14)
Li84Li8Li14Li9650(16) S3Li4Li15Li6106(3)
Li84Li8Li14Li104153(11) S3Li4Li15Li7179(8)
Li84Li8Li14Li13785(17) S3Li4Li15Li12-105(14)
Li84Li8Li14I1525(30) S3Li4Li15I1-99(8)
Li84Li8Li14S5-9(17) S3Li4Li15S13-95.9(14)
Li84Li8Li14S64103(16) S3Li4Li15S21150(2)
Li84Li8Li14S75-116(15) S3Li5Li13Li26(6)
Li96Li8Li14Li15-104(5) S3Li5Li13Li432(5)
Li95Li8Li14Li1570(6) S3Li5Li13Li4283(4)
Li95Li8Li14Li84124(17) S3Li5Li13Li61-80(3)
Li96Li8Li14Li84-50(16) S3Li5Li13Li108-166(6)
Li95Li8Li14Li96174(2) S3Li5Li13Li119119(6)
Li96Li8Li14Li104104(10) S3Li5Li13Li1257(5)
Li95Li8Li14Li104-83(11) S3Li5Li13I19-155.7(13)
Li96Li8Li14Li13735(5) S3Li5Li13S23104.6(10)
Li95Li8Li14Li137-151(3) S3Li5Li13S68-77(16)
Li96Li8Li14I15-24(16) S54Li8Li14Li15136(4)
Li95Li8Li14I15149(14) S5Li8Li14Li15-46(4)
Li95Li8Li14S5115(2) S54Li8Li14Li84-169(20)
Li96Li8Li14S5-58.4(12) S5Li8Li14Li849(17)
Li95Li8Li14S64-133.2(17) S5Li8Li14Li9658.4(12)
Li96Li8Li14S6453.2(17) S54Li8Li14Li96-120(4)
Li95Li8Li14S758(5) S5Li8Li14Li104162(11)
Li96Li8Li14S75-166(3) S54Li8Li14Li104-16(14)
Li104Li8Li14Li15153(15) S5Li8Li14Li13794(5)
Li104Li8Li14Li84-153(11) S54Li8Li14Li137-84(6)
Li104Li8Li14Li96-104(10) S5Li8Li14I1534(15)
Li104Li8Li14Li137-68(10) S54Li8Li14I15-144(12)
Li104Li8Li14I15-128(23) S54Li8Li14S5-178(3)
Li104Li8Li14S5-162(11) S5Li8Li14S64111.6(19)
Li104Li8Li14S64-50(9) S54Li8Li14S64-67(5)
Li104Li8Li14S7591(11) S54Li8Li14S7574(5)
Li114Li8Li14Li1585(5) S5Li8Li14S75-107(3)
Li114Li8Li14Li84139(17) S64Li8Li14Li15-157(6)
Li114Li8Li14Li96-171(2) S64Li8Li14Li84-103(16)
Li114Li8Li14Li104-68(11) S64Li8Li14Li96-53.2(17)
Li114Li8Li14Li137-136(4) S64Li8Li14Li10450(9)
Li114Li8Li14I15164(14) S64Li8Li14Li137-18(3)
Li114Li8Li14S5130.5(15) S64Li8Li14I15-78(15)
Li114Li8Li14S64-117.9(17) S64Li8Li14S5-111.6(19)
Li114Li8Li14S7523(4) S64Li8Li14S75141(4)
Li12Li4Li15Li151(15) S75Li8Li14Li1562(4)
Li12Li4Li15Li420.00(9) S75Li8Li14Li84116(15)
Li12Li4Li15Li52-51(13) S75Li8Li14Li96166(3)
Li12Li4Li15Li6-149(12) S75Li8Li14Li104-91(11)
Li12Li4Li15Li71-176(8) S75Li8Li14Li137-159(7)
Li12Li4Li15I16(21) S75Li8Li14I15141(18)
Li12Li4Li15S139(13) S75Li8Li14S5107(3)
Li12Li4Li15S21-104(14) S75Li8Li14S64-141(4)

11-X,1-Y,1-Z; 21-X,2-Y,1-Z; 3+X,1+Y,+Z; 41-X,-Y,-Z; 5+X,-1+Y,+Z; 61-X,1-Y,-Z; 7-1/2+X,1/2-Y,-1/2+Z; 83/2-X,1/2+Y,1/2-Z; 91/2+X,3/2-Y,1/2+Z

 

Table 7 Atomic Occupancy for Li7Si2S7I_330K.
AtomOccupancy AtomOccupancy AtomOccupancy
Li30.96(3) Li40.33(2) Li50.37(3)
Li60.30(3) Li70.47(3) Li80.47(3)
Li90.48(3) Li100.48(3) Li110.52(3)
Li120.14(3) Li130.28(2) Li140.09(3)
Li150.18(2)     

Experimental

Single crystals of ILi7S7Si2 [Li7Si2S7I_330K] were [?]. A suitable crystal was selected and [] on a dectris-CrysAlisPro-abstract goniometer imported dectris images diffractometer. The crystal was kept at 330.0 K during data collection. Using Olex2 [1], the structure was solved with the SHELXT [2] structure solution program using Intrinsic Phasing and refined with the SHELXL [3] refinement package using Least Squares minimisation.

  1. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H. (2009), J. Appl. Cryst. 42, 339-341.
  2. Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.
  3. Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.

Crystal structure determination of [Li7Si2S7I_330K]

Crystal Data for ILi7S7Si2 (=456.08 g/mol): monoclinic, space group P21/n (no. 14), a = 14.9844(4) Å, b = 6.05530(10) Å, c = 15.1935(4) Å, β = 105.724(3)°, = 1326.99(6) Å3, Z = 4, T = 330.0 K, μ(synchrotron) = 3.367 mm-1, Dcalc = 2.283 g/cm3, 16716 reflections measured (3.282° ≤ 2Θ ≤ 51.006°), 2718 unique (Rint = 0.0477, Rsigma = 0.0232) which were used in all calculations. The final R1 was 0.0359 (I > 2σ(I)) and wR2 was 0.1096 (all data).

Refinement model description

Number of restraints - 71, number of constraints - unknown.

Details:

1. Uiso/Uaniso restraints and constraints
Uanis(Li8) ≈ Ueq, Uanis(Li12) ≈ Ueq, Uanis(Li14) ≈ Ueq: with sigma
of 0.02 and sigma for terminal atoms of 0.04
2. Rigid body (RIGU) restrains
Li4, Li5, Li12, Li13, Li6, Li15, S2, S3
with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
3. Others
1*[Sof(Li3)]+1*[Sof(Li4)]+1*[Sof(Li5)]+1*[Sof(Li6)]+1*[Sof(Li7)]+1*[Sof(Li8)]+
1*[Sof(Li10)]+1*[Sof(Li12)]+1*[Sof(Li13)]+1*[Sof(Li14)]+1*[Sof(Li15)]=4 with
esd of 0.001
1*[Sof(Li9)]+1*[Sof(Li11)]=1 with esd of 0.001

This report has been created with Olex2, compiled on 2022.04.07 svn.rca3783a0 for OlexSys. Please let us know if there are any errors or if you would like to have additional features.